混合配体策略调控钍基MOF增强光催化氧化

来源 :中国化学会第十届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：ben349408481

【摘要】

：

MOF的精准调节进而实现可控制备对于材料的结构和功能意义非凡.基于混合配体策略将卟啉衍生物、线性羧酸配体与六核钍簇结合构筑成新型的卟啉钍基有机框架材料Th-IHEP-5.由于联吡啶配体的引入,光活性卟啉基团的光敏效果进一步增强,Th-IHEP-5对CEES的光催化氧化的效果得到提升.

【作者】

：

黄志伟胡孔球梅雷柴之芳石伟群

【机构】

：

中国科学院高能物理研究所,北京 100049

【出处】

：

中国化学会第十届全国无机化学学术会议

【发表日期】

：

2019年3期

【关键词】

：

混合配体 MOF 卟啉锕系金属 Th 光催化

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混合配体策略调控钍基MOF增强光催化氧化

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