【摘 要】
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Ferrocenes, as well as other planar chiral molecules have recently attracted significant attention in the field of both synthetic chemistry, material science and bioorganometallic chemistry.Ferrocene
【机 构】
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Department of Chemistry, University of Science and Technology of China, 96 JinzhaiRoad, Hefei, Anhui
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Ferrocenes, as well as other planar chiral molecules have recently attracted significant attention in the field of both synthetic chemistry, material science and bioorganometallic chemistry.Ferrocene and its relative structures represent an important and privileged scaffold for some chiral ligands or catalysts.Since the first preparation of an optically active planar chiral ferrocene, specially the development of diastereoselective synthesis of planar chiral ferrocenes from Ugis amine, numerous planar chiral based ligands and catalysts were developed.[1,2] Nowadays ferrocene, as well as binaphthalene, spirobiindane[3]have become three most successful scaffolds for ligands and catalysts in the area of asymmetric catalysis.
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