‘Fastening’ Dyes into the Cross-linked Polyphosphazene: a Novel Strategy to Construct Powerful Fluor

来源 :中国微米纳米技术学会纳米科学技术分会第三届年会暨2014全国纳米生物与医学学术会议 | 被引量 : 0次 | 上传用户:zuiaiyunhao
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It is a significant issue to overcome the concentration-quenching effect of the small fluorescent probes and maintain the high fluorescent efficiency at high concentration for sensitive and selective fluorescent mark or detection.We developed a new strategy to isolate and fasten fluorescent moieties into a highly cross-linked polyphosphazene by the polycondensation of hexachlorocyclotriphosphazene (HCCP) and dibromofluorescein (DBF) or 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin (TPP-(OH)4) in a suitable solvent.
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