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合成了一种新的尾式卟啉铁氯化间一[邻-(4-二乙胺基丁酰胺基)苯基]三苯基卟啉合铁(Ⅲ)(简称meso-MDBPTPPFe(Ⅲ)CI)。用分光光度法研究了meso-MDBPTPPFe(Ⅲ)CI的氧化还原性质及中心离子铁分别为二价和三价时与NO,C0,O_2等双原子小分子及与咪唑、吡啶、二乙胺等有机碱的加合作用。
A novel tricycloporphyrin iron (Ⅲ) (abbreviated as meso-MDBPTPPFe (Ⅲ) CI). The redox properties of meso-MDBPTPPFe (Ⅲ) CI and the study on the redox properties of meso-MDBPTPPFe (Ⅲ) CI were studied by spectrophotometry. Addition of organic bases.