合成了１，１＇－二（Ｎ－萘甲酰腙乙基）二茂铁与一些过渡金属的配合物，通过元素分析、ＩＲ、ＵＶ、热分析和摩尔电导测试结果，对配体与金属离子结合方式、配合物的组成和性质进行了研究；研究结果表明，配体以烯醇式通过亚胺基的氮原子和酰胺基的氧负离子与金属离子配位，生成中性配合物。配合物的热稳定性都比配体的高，配体和配合物都是弱电解质。 The complexes of 1,1’-bis (N-naphthoylhydrazone ethyl) ferrocene with some transition metals were synthesized. The results of elemental analysis, IR, UV, thermal analysis and molar conductance measurements showed that the ligand and metal Ion binding mode, the composition and properties of the complexes were studied. The results show that the ligands form enantioselective complexes by the enol-type reaction of the oxygen anions of the nitrogen and amido groups of the imino group with the metal ions. The thermal stability of the complexes are higher than the ligand, ligands and complexes are weak electrolytes.