The axially deformed relativistic mean field theory with the force NLSH has been performed in the blocked BCS approximation to investigate the properties and structure of N=Z nuclei from Z=20 to Z=48.Some ground state quantities such as binding energies, quadrupole deformations, one/two-nucleon separation energies, root-mean-square (rms) radii of charge and neutron, and shell gaps have been calculated.The results suggest that large deformations can be found in medium-heavy nuclei with N=Z=38-42.The charge and neutron rms radii increase rapidly beyond the magic number N=Z=28 until Z=42 with increasing nucleon number, which is similar to isotope shift, yet beyond Z=42, they decrease dramatically as the structure changes greatly from Z=42 to Z=43.The evolution of shell gaps with proton number Z can be clearly observed.Besides the appearance of possible new shell closures, some conventional shell closures have been found to disappear in some region.In addition, we found that the Coulomb interaction is not strong enough to breakdown the shell structure of protons in the current region.