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采用Gly—GlyOH,4,4＇—联吡啶与Cu(NO_3)_2·H_2O在二次水溶液中反应,合成出以4,4＇—bpy为中继基,Gly—Glyo为螯环新型双核铜配合物。经X射线单晶结构分析确定该配合物品体的化学结构式:[(H_2NCH_2CONHCH_2COO) Cu(OH) (C_(10)H_8N_2)Cu(OH) (H_2NCH_2CONHCH_2COO)]·9H_2O.晶体属于三斜晶系,P_空间群,晶胞参数a=1.1412nm,b=1.2298nm,C=1.4269nm,α=113.82°,β=101.91°,y=103.64°,V=1.6747nm~3,Z=2。衍射数据是在Nicolet XRD R3型四圆衍射仪上收集,结构参数经块矩阵最小二乘法精修后,最终一致性因子R值为0.068,RW值为0.057。
Using Gly-GlyOH, 4,4’-dipyridyl and Cu (NO_3) _2 · H_2O were reacted in the secondary aqueous solution to synthesize 4,4’-bpy as the relay and Gly-Glyo as the new dual binuclear copper Complex. The chemical structure of the complex was confirmed by X-ray single crystal structure analysis: [(H_2NCH_2CONHCH_2COO) Cu (OH) (C_ (10) H_8N_2) Cu (OH) _ Space group with unit cell parameters a = 1.1412 nm, b = 1.2298 nm, C = 1.4269 nm, α = 113.82 °, β = 101.91 °, y = 103.64 °, V = 1.6747 nm -3, Z = 2. The diffraction data were collected on a Nicolet XRD R3 four-circular diffractometer. After the structural parameters were refined by the least squares method of block matrix, the final consistency factor R value was 0.068 and the RW value was 0.057.