论文部分内容阅读
研究了双组分混合弱酸溶液〔H+〕近似计算时忽略水离解的条件和平方加和法则的适用性。当较强酸的浓度(C1)满足C1≥bKa1(b值范围05~8,与C1/C2、Ka1/Ka2等值有关)时,使用平方加和法则计算〔H+〕的误差较小(|RE|≤±23%)。
The applicability of neglecting the conditions of water dissociation and the square addition rule for the approximate calculation of [H +] in a two-component mixed weak acid solution was studied. When the stronger acid concentration (C1) satisfies C1 ≥ bKa1 (b value range is 0.5-5, which is related to C1 / C2, Ka1 / Ka2, etc.), the error of using the square addition law to calculate [H +] is small | RE | ≤ ± 2.3%).