论文部分内容阅读
对四-间甲基-苯基卟啉H2T(m－CH3)PP与Zn（Ⅱ）、Cd（Ⅱ）、Hg（Ⅱ）在丙酮中、四苯基卟啉H2TPP与Zn（Ⅱ）在丙固和DMF中的生成反应动力学进行了研究,根据我们的实验结果和对前人工作的总结，提出了较为合理的反应机理，用非线性拟合的方法求得各基无步骤的动力学参数．合理解释了锌、镉、汞卟啉生成反应体系的区别，探讨了温度和溶剂对该反应体系的影响．
In tetraphenylporphyrin H2TPP with Zn (Ⅱ), Cd (Ⅱ) and Hg (Ⅱ) in acetone, the tetraphenylporphyrin H2TPP and Zn (Ⅱ) The kinetics of formation reaction in solid and DMF was studied. According to our experimental results and the summary of previous work, a more reasonable reaction mechanism was proposed. The non-linear kinetics parameter. The differences between zinc, cadmium and mercury porphyrin reaction systems were explained reasonably, and the effects of temperature and solvent on the reaction system were discussed.