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The hydrothermal reaction of CdCl2with 1,3,4-thiadiazole-2,5-dithiol affords one 2D network cadmium(Ⅱ) coordination polymer, [Cd(5-thioxo-4,5-dihydro-1,3,4-thiadiazole-2-thiolate)2]n. The structure was determined by single crystal X-ray diffraction, the c