【摘 要】
：
The redox initiation system for polyacrylate sodium of high molecular mass was designed and its effect with varying component dosage on the degree of polymeriza
【机 构】
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School of Chemistry and Chemical Engineering
【基金项目】
：
国家重点基础研究发展计划(973计划)
论文部分内容阅读
The redox initiation system for polyacrylate sodium of high molecular mass was designed and its effect with varying component dosage on the degree of polymerization was investigated. The results show that the proper type and amount of inorganic salt, as well as amine initiator, are conductive to the increase of degree of polymerization. The fine ingredient of the initiation system is as follows:the dosages of amine, persulphate and inorganic salt are 0.75%, 0.10% and 1.00% by mass based on acryl acid respectively, the molar ratio of sulphite to the persulphate is 1:1. Under such conditions the degree of polyacrylate can reach 7.43×107 with a acceptable polymerization time for industrial production.
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