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The solvothermal reaction of 3-amino-1H-1,2,4-triazole (ttr) with Zn(ClO4)2·6H2O and NaCl in a 1:1:1 molar ratio gave a new complex [Zn(ttr)Cl]n with a 3-connected (4.82) 2-D struc- ture. The layers stack in the -ABAB- way along the c axis with abundant hydrogen bonding interac- tions to form the crystal structure. The complex [Zn(ttr)Cl]n crystallizes in the orthorhombic space group Pbca with a = 9.369(1), b = 10.049(1), c = 11.905(1) , V = 1120.9(3) 3, Z = 8.00, C2N4H3ZnCl, Mr = 183.90, Dc = 2.180 g/cm3, μ = 4.740 mm-1, F(000) = 720, S = 1.059 and T = 293(2) K. The final R = 0.0662 and wR = 0.2457 for 956 observed reflections with I > 2σ(I), and R = 0.0689 and wR = 0.2504 for all data.
The solvothermal reaction of 3-amino-1H-1,2,4-triazole (ttr) with Zn (ClO4) 2 · 6H2O and NaCl in a 1: 1: 1 molar ratio gave a new complex [Zn (ttr) Cl] The layers stack in the -ABAB-way along the c axis with abundant hydrogen bonding interactivity to the crystal structure. The complex [Zn (ttr) Cl ] n crystallizes in the orthorhombic space group Pbca with a = 9.369 (1), b = 10.049 (1), c = 11.905 1 V = 1120.9 (3) 3, Z = 8.00, C2N4H3ZnCl, Mr = 183.90 D = 2.180 g / cm3, μ = 4.740 mm-1, F (000) = 720, S = 1.059 and T = 293 (2) K. The final R = 0.0662 and wR = 0.2457 for 956 observed reflections with I> 2σ (I), and R = 0.0689 and wR = 0.2504 for all data.