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The complex(2-pyridinecarboxylato) 2 diphenyltin?was synthesized by the reaction of 2-pyridinecarboxylic acids with the diphenyltin?oxide.The crystal structure was determined by X-ray diffraction.The crystal belongs to monoclinic with space group P2 1 /n,a=1.46504(19)nm,b=1.01225(13)nm,c=1.45406(19)nm,β=94.849(2)°,Z =4,R 1 =0.0285,w R 2 =0.0672.In this complex,the tin ato m rendered six-coordinate in a distorted octahedron geometry.Eac h central tin atom is surrounded equatorial by two oxygen atoms coming fro m two carboxyl groups,one nitrogen atom c oming from pyridinyl group and one carbon atom of the penyl group and axially by one carbon atom of the phenyl group and one nitrogen atom coming from pyridinyl group.CCDC:180021.
The complex (2-pyridinecarboxylato) 2 diphenyltin? Was synthesized by the reaction of 2-pyridinecarboxylic acids with the diphenyltin? Oxide. The crystal structure was determined by X-ray diffraction. The crystal belongs to monoclinic with space group P2 1 / n, a = 1.46504 (19) nm, b = 1.01225 (13) nm, c = 1.45406 (19) nm, β = 94.849 (2) °, Z = 4, R 1 = 0.0285, w R 2 = 0.0672.In this complex , the tin ato m rendered six-coordinate in a distorted octahedron geometry. Eh h central tin atom is surrounded equatorial by two oxygen atoms coming fro m two carboxyl groups, one nitrogen atom c oming from pyridinyl group and one carbon atom of the penyl group and axially by one carbon atom of the phenyl group and one nitrogen atom coming from pyridinyl group. CCDC: 180021.