【摘 要】
:
Finite element method is used to simulate the high-speed melt spinning process, based on the equation system proposed by Doufas et al. Calculation predicts a ne
【机 构】
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Department of Polymer Materials Science & Engineering
【基金项目】
:
国家自然科学基金;国家科技攻关项目;the Doctoral Foundation of National Education Committee of China
论文部分内容阅读
Finite element method is used to simulate the high-speed melt spinning process, based on the equation system proposed by Doufas et al. Calculation predicts a neck-like deformation, as well as the related profiles of velocity, diameter, temperature, chain orientation, and crystallinity in the fiber spinning process. Considering combined effects on the process such as flow-induced crystallization, viscoelasticity, filament cooling, air drag, inertia, surface tension and gravity, the simulated material flow behaviors are consistent with those observed for semi-crystalline polymers under various spinning conditions. The structure change of polymer coils in the necking region described by the evolution of conformation tensor is also investigated. Based on the relaxation mechanism of macromolecules in flow field different types of morphology change of polymer chains before and in the neck are proposed, giving a complete prospect of structure evolution and crystallization of semi-crystalline polymer in the high speed fiber spinning process.
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