【摘 要】
：
A novel chiral copper(Ⅱ) complex with racemic 1,2-diaminocyclohexane and iodide,[Cu(Ⅱ)(1,2-diaminocyclohexane)_3](I)_2·3H_2O(1) has been synthesized and stru
【机 构】
：
School of Physics and Materials Engineering,Dalian Nationalities University,
论文部分内容阅读
A novel chiral copper(Ⅱ) complex with racemic 1,2-diaminocyclohexane and iodide,[Cu(Ⅱ)(1,2-diaminocyclohexane)_3](I)_2·3H_2O(1) has been synthesized and structurally characterized by X-ray single-crystal diffraction,elemental analysis,infrared spectroscopy,Raman spectroscopy and thermogravimetric analysis. In complex 1,the CuⅡ ion was coordinated by six nitrogen atoms of three 1,2-diaminocyclohexane molecules. The structure of complex 1 can be described as a supramolecular 3D-like structure which was formed by intermolecular hydrogen-bonding interactions between mononuclear molecules,uncoordinated water molecules and two iodide anions. UV-vis absorption spectrum and surface photovoltage properties of complex 1 have also been studied.
A novel chiral copper (Ⅱ) complex with racemic 1,2-diaminocyclohexane and iodide, [Cu (Ⅱ) (1,2-diaminocyclohexane) _3] ray single-crystal diffraction, elemental analysis, infrared spectroscopy, Raman spectroscopy and thermogravimetric analysis. In complex 1, the Cu ion was coordinated by six nitrogen atoms of three 1,2-diaminocyclohexane molecules. supramolecular 3D-like structure which was formed by intermolecular hydrogen-bonding interactions between mononuclear molecules, uncoordinated water molecules and two iodide anions. UV-vis absorption spectrum and surface photovoltage properties of complex 1 have also been studied.
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