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S44-23 MCPBA氧化芳基硼酸制备苯酚的新法Chen DS等[Synlett,2013,(24):0499]芳基硼酸与等摩尔量的间氯过氧苯甲酸(MCPBA)室温反应6 h制得相应的苯酚,溶剂优选水-乙醇(1∶2),10例收率80%～100%。反应条件温和,无需碱、金属催化剂及配体。
S44-23 New method for the preparation of phenol by oxidation of aryl boronic acids with MCPBA Chen DS et al. [Synlett, 2013, (24): 0499] The reaction of arylboronic acid with an equimolar amount of m-chloroperoxybenzoic acid (MCPBA) Phenol, the solvent is preferably water - ethanol (1: 2), 10 cases of 80% to 100% yield. The reaction conditions are mild, without alkali, metal catalysts and ligands.