合成了 8-羟基喹啉合钴 ( )·甲醇加合物并测定其晶体结构 .该晶体属于单斜晶系的 P2 (1 ) / n空间群 .a=1 .0 91 8(± 2 ) mm,b=1 .3 1 3 6(± 8) nm,c=1 .6699(± 3 ) nm,β=97.5 8(± 3 )°,V=2 .3 74 0(± 8) nm3,Z=4 ,F(0 0 0 ) =1 0 80 . 8-羟基喹啉合钴 ( )配合物中钴原子为六配位的变形八面体构型 ,它的甲醇加合物通过氢键形成了二维超分子晶体结构 The crystal structure of 8-hydroxyquinoline cobalt () · methanol adduct was synthesized and the crystal belongs to the monoclinic P2 (1) / n space group with a = 1.091 8 (± 2) mm, b = 1.3136 ± 8 nm, c = 1.6699 ± 3 nm, β = 97.5 8 ± 3 °, V = 2.374 ± 8 ± nm3, Z = 4, F (0 0 0) = 1 0 80. 8-hydroxyquinoline cobalt () complex cobalt atom hexacoordinated deformed octahedral configuration, its methanol adduct formed by hydrogen bonding Two-dimensional supramolecular crystal structure