Phase Behavior and Interfacial Properties of Diblock Copolymer-Homopolymer Ternary Mixtures: Influen

来源 :Chinese Journal of Polymer Science | 被引量 : 0次 | 上传用户:flurryzhang
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We use a Monte Carlo method to study the phase and interfacial behaviors of A-b-B diblocks in a blend of homopolymers, A and B, which are confined between two asymmetric hard and impenetrable walls. Our results show that, when the interaction strength is weak, the block copolymersare uniformly distributed in the ternary mixtures under considered concentrations. Under strong interaction strength, distribution region of the block copolymers changes from a single smooth interface to a curved interface or multi-layer interface in the ternary mixtures. Furthermore, our findings show that with increasing volume fraction of A-b-B diblock copolymer(фC), copolymer profiles broaden while фC≥ 0.4, a lamellar phase is formed and by further increasing фC, more thinner layers are observed. Moreover, the results show that, with the increase of фC, the phase interface first gradually transforms from plane to a curved surface rather than micelle or lamellar phase while with the increase of the interaction between A and B segments(ε_(AB)), the copolymer chains not only get stretched in the direction perpendicular to the interface, but also are oriented. The simulations also revealthat the difference between symmetric and asymmetric copolymers is negligible in statistics if the lengths of two blocksare comparable. We use a Monte Carlo method to study the phase and interfacial behaviors of AbB diblocks in a blend of homopolymers, A and B, which are confined between two asymmetric hard and impenetrable walls. Our results show that, when the interaction strength is weak, the block copolymersare uniformly distributed in the ternary mixtures under considered concentrations. Under strong interaction strength, distribution region of the block copolymers changes from a single smooth interface to a curved interface or multi-layer interface in the ternary mixtures. increasing volume fraction of AbB diblock copolymer (фC), copolymer profiles broaden while фC ≧ 0.4, a lamellar phase is formed and by further increasing фC, more thinner layers are observed. phase interface first gradually transforms from plane to a curved surface rather than micelle or lamellar phase while with the increase of the in teraction between A and B segments (ε_ (AB)), the copolymers chains not only get stretched in the direction perpendicular to the interface, but also are oriented. The simulations also reveal the difference between symmetric and asymmetric prints is negligible in statistics if the lengths of two blocksare comparable.
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