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The title complex bis(4-aminophenylacetate)triphenylantimony(V) has been synthesized by the reaction of triphenylantimony dibromide with 4-aminophenylacetic acid in 1∶2 molar ratio. The complex was characterized by elemental analysis,IR spectra,NMR (1H,13C) and X-ray diffraction crystal structure analysis. This complex crystallizes in the monoclinic system,space group C2/c with a=2.279 4(2) nm,b=0.957 10(10) nm,c=1.335 49(15) nm,β=93.781(2)°. The molecular structure adopts a distorted trigonal bipyramidal geometry around the antimony atom. In the crystal structure molecules are connected by intermolecular N-H …O hydrogen-bonding interactions forming a two-dimensional network structure. CCDC:726039.
The title complex bis (4-aminophenylacetate) triphenylantimony (V) has been synthesized by the reaction of triphenylantimony dibromide with 4-aminophenylacetic acid in 1: 2 molar ratio. The complex was characterized by elemental analysis, IR spectra, NMR (1H, 13C This complex crystallizes in the monoclinic system, space group C2 / c with a = 2.279 4 (2) nm, b = 0.957 10 (10) nm, c = 1.335 49 , β = 93.781 (2) °. The molecular structure of a distorted trigonal bipyramidal geometry around the antimony atom. In the crystal structure molecules are connected by intermolecular NH ... O hydrogen-bonding interactions forming a two-dimensional network structure. CCDC: 726039 .