Dephosphorization behavior of monazite concentrate with charred coal at high temperature was investigated. It is found that the roast temperature is the main factor for the dephosphorization of the monazite. The high dephosphorization efficiency can be reached at the temperatures ranging from 1 200 to 1 400 ℃. When the monazite pellets, made by pressing mixture of the monazite, charred coal and water into mould, were roasted at 1 400 ℃ for 2 h, 98% of phosphorus was removed from the monazite pellets. The roast time has little effect on the dephosphorization efficiency. Meanwhile, the particle size of the charred coal also has great influence on the dephosphorization efficiency of the monazite, and it is better to control particle size around 150 μm, while Fe and Fe2O3 have neglectable effect on the dephosphorization of the monazite.