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The electrochemical behavior of tetranuclear molybdenum cluster [Mo4S4 (μ-dtp)2 (dtp)43 (1) (dtp = S2P (OEt)2) has been investigated by cyclic voltammetry, potentiotatic polarization measurement, controlled potential coulometry and pulse polarography. It is demonstrated that the compound undergoes two consecutive near reversible one-electron reductions at 0. 01V and -0. 77V , respectively and a near reversible one-electron oxidation at 1. 01V with scan rates from 25mV/sec to 1V/sec in cyclic voltammetric measurements. The cluster compound displays three redox processes, indicating its high structural stability.
The electrochemical behavior of tetranuclear molybdenum cluster [Mo4S4 (μ-dtp) 2 (dtp) 43 (1) (dtp = S2P (OEt) 2) has been investigated by cyclic voltammetry, potentiotronic polarization measurement, controlled potential coulometry and pulse polarography. is demonstrated that the compound undergoes two consecutive near reversible one-electron reductions at 0. 01V and -0. 77V, respectively and a near reversible one-electron oxidation at 1. 01V with scan rates from 25mV / sec to 1V / sec in cyclic voltammetric measurements. The cluster compound displays three redox processes, indicating its high structural stability.