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Crystal structure of the title compound, Cu(phen) (H2O) 2 @ C1O4(phen = 1, 1O-phenanthroline), was deter-mined by X-ray crystallography. It crystallizes in the monoclinic system, space group C2/c with lattice parametersa = 1. 49071 (4) nm, b = 1. 38594(4)