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Amorphous metallic coatings with a composition of Fe48Cr15Mo14C15B6Y2 were prepared by means of atmospheric plasma spraying (APS) process under different conditions. The microstructure and frictional behavior were characterized simultaneously in this article. The results show that the as-deposited coatings consist of amorphous matrix and some precipitated nanocrystals, while the amorphous fraction and particle deformation as well as crystallization mechanism are significantly sensitive to the spraying parameters. The amorphous coatings express high microhardness and excellent wear resistance under dry frictional wear condition, which attributes to the inherent characteristic of amorphous phase and the dispersion strengthening of precipitated nanocrystals. The dominant wear mechanism of the amorphous coatings is fatigue wear accompanying with oxidative wear. In addition, the microhardness and wear resistance of the amorphous coatings were improved by optimizing spraying parameters, owing to the effect of both structural character and proper proportional of amorphous and nanocrystals fraction.
The microstructure and frictional behavior were characterized simultaneously in this article. The results show that the as-deposited coatings consist of amorphous matrix and some precipitated nanocrystals, while the amorphous fraction and particle deformation as well as crystallization mechanisms are significantly sensitive to the spraying parameters. The amorphous coatings express high microhardness and excellent wear resistance under dry frictional wear conditions, which attributes to the inherent characteristic of amorphous phase and the dispersion strengthening of precipitated nanocrystals. The dominant wear mechanism of the amorphous coatings is fatigue wear accompanying with oxidative wear. In addition, the microhardness and wear resistance of the amorphous coatings were improved by optimizing spraying parameters, owin g to the effect of both structural character and proper proportional of amorphous and nanocrystals fraction.