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合成了O 乙基二硫代碳酸铋配合物。通过元素分析、红外光谱和X 射线单晶衍射对其结构进行了表征。测试结果表明 :该配合物为三斜晶系 ,空间群P墿,a =1 0 5 5 1(3)nm ,b =1 933(3)nm ,c=1 4 15 3(3)nm ,α =92 0 77(3)°,β =90 4 5 1(4 )°,γ =10 0 5 37(3)° ,Z =4 ,V =1 75 0 5 (7)nm3 ,Dc =2 173g/cm3 ,μ(MoKα) =10 786mm-1,F(0 0 0 ) =10 88,R1=0 0 5 0 0 ,wR2 =0 0 718。在晶体中 ,配合物分子间通过Bi…O和Bi…S弱相互作用 ,形成一维链状结构
Synthesis of O ethyl dithiocarbonate bismuth complex. Its structure was characterized by elemental analysis, infrared spectroscopy and X-ray single crystal diffraction. The results show that the complex is triclinic with space group P 墿, a = 1 0 5 5 1 (3) nm, b = 1 933 (3) nm and c = 1 4 15 3 α = 92 0 77 (3) °, β = 90 4 5 1 (4) °, γ = 10 0 5 37 (3) °, Z = 4, V = 1 75 0 5 (7) nm3, Dc = 2 173 g / cm3, μ (MoKα) = 10 786 mm-1, F (0 0 0) = 10 88, R1 = 0 0 5 0 0, and wR2 = 0 0 718. In the crystal, the complex molecules weakly interact with each other via Bi ... O and Bi ... S to form a one-dimensional chain structure