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本文表明含炔键的单簇铁硫配合物(μ-PhC≡S)(μ-RS)Fe_2CO)_6 1,在乙醚和室温条件下与Co_2(CO)_8发生络合反应,生成铁硫和钴碳双簇配合物μ-[(OC)_5Co_2PhC_2S](μ-RS)Fe_2(CO)_5 2.本文还表征了双簇配合物2的结构并对R与硫桥原子所连的键型以及影响络合反应的空间位阻因素进行了讨论。
In this paper, it has been shown that the single-group iron-sulfur complex (μ-PhC≡S) (μ-RS) Fe_2CO) _6 with acetylenic bonds undergoes complexation with Co_2 (CO) Cobalt-carbon double-cluster complexes μ - [(OC) _5Co_2PhC_2S] (μ-RS) Fe_2 (CO) _5 2. We also characterize the structure of the double-cluster complex 2 and characterize the bond- The spatial steric factors affecting the complexation reaction are discussed.