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根据本发明,在温和反应条件下,通过液相反应从烯丙基化合物中直接反应生成具有烯丙基位的不饱和伯醇或不饱和醚。烯烃化合物在使用奎宁作为氧化剂和均相钯催化剂存在下,由分子式(a)与二氧化碳和分子式(Ⅰb)的水反应,溶剂中的亲核试剂和不饱和醇具有烯丙基链接得到分子式(Ⅰc)。通过使用二氧化碳/醇体系、苯酚或其衍生物作为亲核剂,可以得到具有烯丙基位置的不饱和醚。(式中,R1表示任选取代的直链或支链的烷基1~5个碳原子,
According to the present invention, an allylic unsaturated primary alcohol or an unsaturated ether is directly generated from an allyl compound by a liquid phase reaction under mild reaction conditions. The olefin compound is reacted with carbon dioxide and water of formula (Ib) in the presence of quinine as an oxidizing agent and a homogeneous palladium catalyst with an allylic linkage of a nucleophile and an unsaturated alcohol in the solvent to give a compound of formula Ic). By using a carbon dioxide / alcohol system, phenol or a derivative thereof as a nucleophilic agent, an unsaturated ether having an allylic position can be obtained. (Wherein R1 represents an optionally substituted linear or branched alkyl group of 1 to 5 carbon atoms,