本文概述近十几年来聚合物固体电解质材料开发研究的状况,包括线型高分子、为改进性能而发展起来的枝型、梳型及交联型高分子,并对高分子与金属盐络合的离子聚合物结构和性能作了描述。阐述了高分子固体电解质的导电行为、导电模型及导电机理。对聚合物固体电解质的各种应用作了介绍并简要讨论了高分子固体电解质的发展趋向及前景。 This article summarizes the research and development of polymer solid electrolyte materials in recent ten years, including linear polymers, branched type, comb type and cross-linked type polymers developed to improve performance, and the complexation of polymer and metal salt The ionic polymer structure and properties are described. The conductive behavior, conduction model and conduction mechanism of polymer solid electrolyte are described. Various applications of polymer solid electrolytes were introduced and the development trends and prospects of polymer solid electrolytes were briefly discussed.