【摘 要】
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Main observation and conclusionrnAn efficient catalytic system was successfully developed on reduction of N-heteroaromatics with H3N·BH3 as hydrogen source in CuSO4 solution,featuring excellent chemoselectivity as well as very broad functional group toler
【机 构】
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Institute of Next Generation Matter Transformation,College of Chemical Engineering and College of Ma
论文部分内容阅读
Main observation and conclusionrnAn efficient catalytic system was successfully developed on reduction of N-heteroaromatics with H3N·BH3 as hydrogen source in CuSO4 solution,featuring excellent chemoselectivity as well as very broad functional group tolerance.Various challenging substrates,such as OH-,NH2-,Cl-,Br-,etc.,contained quinolines,quinoxalines,1,5-naphthyridines and quinazolines were all reduced smoothly.Mechanistic studies suggested that [Cu-H] intermediate might be generated from NH3·BH3,which was believed to form with H3N·BH3 in CuSO4 solution.
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