Reaction performance of fluidized bed catalytic reactor of Group C+particles

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Group C particles are often regarded as non-fluidizable but have proven to effectively fluidize with nanoparticle addition,which results in small bubbles and a high gas holdup in the dense phase during the experiments.Group C+particles provide an increased surface area for gas-solid contact and improve the reaction performance,especially for gas-phase catalytic reactions.On the basis of a previous study of the ozone decomposition reaction using Group C+particles,a two-phase model was used to evaluate the reactor contact efficiency,and was used to compare the partial oxidation performance of the n-butane to maleic anhydride reaction in fluidized-bed catalytic reactors of Group C+and Group A particles.The reactor with Group C+particles achieved a higher n-butane conversion and MAN yield compared with that using Group A particles,based on the identical catalyst quantity or on the same gas residence time.Therefore,the reactor with Group C+particles can achieve the same reaction conversion and yield with fewer catalysts or a smaller reactor size,or both.Therefore,the fluidized bed catalytic reactor of Group C+particles is expected to be of major significance in industrial processes,especially for gas-phase catalytic reactions.
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