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用玻璃外循环无梯度反应器研究了丁烯异构化 L-H 机理复杂反应动力学.用正交设计法估计了动力学方程中的参数.色谱法测定了丁烯吸附热.异构化生成反-2-丁烯及顺-2-丁烯的动力学方程分别为(7)式和(8)式.
The kinetics of the complex reaction of isomerization of butene (LH) was studied by using a glass-free external loop gradientless reactor.The parameters in the kinetic equation were estimated by orthogonal design.The adsorption heat of butene was determined by chromatography.The isomerization reaction The kinetic equations of 2-butene and cis-2-butene are (7) and (8) respectively.