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以2-醛基吡啶和1,2-二(对氨基苯氧基)乙烷进行缩合得到Schiff碱配体L,然后与AgSbF6进行配位反应,得到了席夫碱配合物[Ag(L)SbF6]n,用元素分析、FT-IR和X-射线单晶衍射进行了表征.结果表明,配合物属于单斜晶系,P21/n空间群,每个Ag(Ⅰ)的配位环境均为扭曲四面体,每个配体L通过其两端的2个N原子同2个金属离子配位桥联形成一维螺旋链结构.
The Schiff base ligand L was obtained by condensation of 2-aldehyde pyridine with 1,2-bis (p-aminophenoxy) ethane and then coordinated with AgSbF6 to obtain Schiff base complex [Ag (L) SbF6] n was characterized by elemental analysis, FT-IR and single crystal X-ray diffraction. The results show that the complex belongs to the monoclinic space group P21 / n, and the coordination environment of each Ag To distort the tetrahedron, each ligand L forms a one-dimensional helical-chain structure through the coordination of two N atoms at two ends with two metal ions.