用 KOH 作催化剂,苯作溶剂使有机基团三乙氧基硅烷和 N,N-双(β-羟乙基)丙醇胺或N,N-双(β-羟丙基)丙醇胺发生酯交换反应,合成了7种新的分子内带一个六元环结构的杂氮硅三环类化合物,并用 IR、MS、~1HNMR 和 XPS 等测定了它们的结构。实验结果表明,这些化合物的环骨架结构是稳定的,且在其分子内存在 N→Si 配位键。 Using KOH as a catalyst, a benzylic solvent is used to make the organic group triethoxysilane and N, N-bis (β-hydroxyethyl) propanolamine or N, N-bis Transesterification reaction, seven kinds of novel azido-tricyclic compounds with a six-membered ring structure were synthesized and their structures were determined by IR, MS, 1HNMR and XPS. The experimental results show that the ring structure of these compounds is stable, and there are N → Si coordination bonds in their molecules.