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用十六烷基三辛基铵四苯硼(CTOATPB),十六烷基三苯基四苯硼(CTTPTPB),四丁基铵二苦胺(TBADPA),四丁基铵雷氏盐(TBARKS)和四丁基铵磷钨酸(TBAPT)五种离子化合物作为两不互溶电解质溶液界面的有机相基础电解质,测定了它们在1,2-二氯乙烷中的缔合常数,研究了它们组成的界面的阻抗行为和由它们确定的电位窗范围.CTOATPB和CTPPTPB的电位窗朝负方向扩展,使用TBATPB无法观察到的Br,Ⅰ和ClO_4的迁移波能够被观察到,能够用来研完强亲水性的阴离子从水相到有机相或强亲脂性的阳离子从有机相到水相的迁移行为,是两种性能优于TBATPB的新型基础电解质溶液.
Cetyltrimethylammonium tetraphenylborate (CTOATPB), cetyltriphenylbenzenetetraphenylboron (CTTPTPB), tetrabutylammonium ditramide (TBADPA), tetrabutylammonium bromide (TBARKS ) And tetrabutylammonium phosphotungstic acid (TBAPT) as the organic phase basic electrolytes at the interface of two immiscible electrolyte solutions, their association constants in 1,2-dichloroethane were measured and their And the potential window defined by them.The potential window of CTOATPB and CTPPTPB extends in the negative direction and the migration waves of Br, I and ClO_4 that can not be observed with TBATPB can be observed and can be used to study The migration of strongly hydrophilic anions from aqueous phase to organic phase or strongly lipophilic cations from organic phase to aqueous phase are two new basic electrolyte solutions with better performance than TBATPB.