【摘 要】
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The title complex [RuH(CO)(PPh)(4-ClPhNHCS)]-CH has been prepared and characterized by X-ray diffraction analysis.It crystallizes in the triclinic system, space
【机 构】
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Institute of Molecular Engineering and Applied Chemistry
论文部分内容阅读
The title complex [RuH(CO)(PPh)(4-ClPhNHCS)]-CH has been prepared and characterized by X-ray diffraction analysis.It crystallizes in the triclinic system, space group Pi with a = 11.0817(2), b = 14.3889(2), c = 15.2136(2)(A), a = 71.018(1), β = 74.911(1), γ= 85.146(1)°, V = 2214.86(6) (A), M = 900.40,μ(MoKa) = 0.616 mmligand via two sulfur atoms.The average Ru-S, Ru-P and Ru-H bond lengths are 2.4824(8), 2.3495(8) and 1.71(2) (A), respectively.The electrochemical properties of 1 have been studied in CHCl solution by cyclic voltammetry.
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