【摘 要】
：
The single crystal of bi (8-hydroxyquinoline) bihydrated cobalt ( Ⅱ ) complex, [ Co ( Q)2 ( H2O)2 ] (Q = 8-hydroxyquinoline ion), has been synthesized by gener
【机 构】
：
School of Science
【基金项目】
：
国家自然科学基金;高等学校博士学科点专项科研项目
论文部分内容阅读
The single crystal of bi (8-hydroxyquinoline) bihydrated cobalt ( Ⅱ ) complex, [ Co ( Q)2 ( H2O)2 ] (Q = 8-hydroxyquinoline ion), has been synthesized by general method and structurally characterized by single crystal X-ray diffraction. Crystal data: C18H16CoN2O4, monoclinic, C2/c, a = 1.336 2(4) nm, b = 0.941 2(3) nm, c = 1.354 3(4) nm, β= 109.672(4)°, Z= 4. In the complex, Co( Ⅱ ) ion is six-coordinated, forming a distorted octahedron. H-bonding and π-π stacking interaction play a significant role to form and stabilize the three-dimensional structure.
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