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从芳基二茂铁的汞化产物中首次分离出四种异环二取代产物1-氯汞基-1’-芳基二茂铁。1-氯汞基-1’-芳基二茂铁与碘作用得到四种相应的碘代产物。氯汞基二茂铁及1-氯汞基-1’-芳基二茂铁经[ClRh(CO)_2]_2催化偶联反应制得联二茂铁和三种1’、1-二芳基联二茂铁。以上化合物的组成与结构经元素分析、IR和~1H NMR确证,其中10种为新化合物。
For the first time, four heterobicyclic disubstituted products, 1-chloromercur-1’-arylferrocene, were isolated from the amalgaminated products of arylferrocenes. The reaction of 1-chloromercur-1’-arylferrocene with iodine gives four corresponding iodide products. Chloride-based ferrocene and 1-chloro- mercuryl-1’-arylferrocene by [ClRh (CO) 2] 2 catalytic coupling reaction of ferrocene and three kinds of 1 ’ Kell Ferrocene. The composition and structure of the above compounds were confirmed by elemental analysis, IR and ~ 1H NMR, of which 10 were new compounds.