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A silver(Ⅰ) complex has been obtained from reaction of silver salt and 4-Hpytz(4-Hpytz=3,5-di(4-pyridyl)-1,2,4-triazole) by hydrothermal method.Single crystal structure reveals that it consists of a 2D coordination polymer [Ag(4-pytz)]∞(1)(4-pytz=3,5-di(4