Layer-dependent charge density wave phase transition stiffness in 1T-TaS2 nanoflakes evidenced by ul

来源 :纳米研究(英文版) | 被引量 : 0次 | 上传用户:zpe3werv
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Novel physical properties emerge when the thickness of charge density wave (CDW) materials is reduced to the atomic level,owing to the significant modification of the electronic band structure and correlation effects.Here,we investigate the layer-dependent CDW phase transition and evolution of the nonequilibrium state of 1T-TaS2 nanoflakes using pump-probe spectroscopy.Both the low-energy single-particle and collective excitation relaxations exhibit sharp changes at ~ 210 K,indicating a phase transition from commensurate CDW to nearly commensurate CDW state.The single particle process reveals that the phase transition stiffness(PTS) is thickness-dependent.Moreover,a small PTS is observed in thin nanoflakes,which is attributed to the reduced thickness that increases the fluctuation and inhibits the nucleation and growth of discommensurations.In addition,the phase mode vanishes when the discommensuration network appears.Our results suggest that the carrier dynamics could be an efficient operational approach to measuring the quantum phase transition in correlated materials.
其他文献
Support materials play a significant role in heterogeneous nanocatalysis.In this work,β-cyclodextrin (β-CD) was used directly as a monomer to construct polyme
为了提高混凝土结构抗硫酸盐侵蚀,采用共沉淀法制备钴铁镁铝四元水滑石,采用固相混合法制备钴铁镁铝水滑石-碳纳米管复合材料。将其应用于水泥净浆中,研究了龄期、浓度对固化硫酸根离子性能的影响,结果表明:和普通水泥净浆相比,加入钴铁镁铝水滑石-碳纳米管后,对SO2-4固化能力得到了明显的提升,在7 d,SO2-4浓度为0.05 mol/L时,其固化量由97.46 mg/g增加到107.11 mg/g;CoFeMgAl-LDHs
研究了铀溶液初始pH、HCO-3质量浓度和硫化纳米零价铁(sulfidized nano-scale zerovalent iron,SnZVI)投加量对SnZVI去除铀的动力学过程的影响,并通过SEM、XRD和XPS阐明SnZVI去除铀的机理。球形SnZVI颗粒直径为100~200 nm,比表面积为43.5 m2/g。SnZVI颗粒中含有Fe和FeS,且Fe(0)和Fe(Ⅱ)含量超过80%。SnZVI去除铀的动力学过程符合准一级动力学模型
Two-dimensional (2D) materials,such as transition metal dichalcogenides (TMDs),black phosphorus (BP),MXene and borophene,have aroused extensive attention since
Silicon is a low price and high capacity anode material for lithium-ion batteries.The yolk-shell structure can effectively accommodate Si expansion to improve s
The demand for high-performance non-precious-metal electrocatalysts to replace the noble metal-based catalysts for oxygen reduction reaction (ORR) is intensivel
Hexagonal molybdenum carbide (Mo2C) as an effective non-noble cocatalyst is intensively researched in the photocatalytic H2-evolution field owing to its Pt-like
Herein,a two-dimensional (2D) interspace-confined synthetic strategy is developed for producing MoS-2-intercalated graphite (G-MoS2)hetero-layers composite thro
Although tremendous efforts have been paid on electrocatalysts toward efficient electrochemical hydrogen generation,breakthrough is still highly needed in the d
Understanding the interaction of nanomaterials with biological systems has always been of high concem and interest.An emerging type of nanomaterials,ultrasmall