【摘 要】
：
A novel 1,6-hexamethylenediamine-zincophosphite has been synthesized hydrothermally. Its single-crystal structure refinement has shown the zincophosphite with t
【机 构】
：
Institute of New Catalytic Material Science, College of Chemistry, Nankai University,Institute of Ne
【出 处】
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Chinese Journal of Chemistry
论文部分内容阅读
A novel 1,6-hexamethylenediamine-zincophosphite has been synthesized hydrothermally. Its single-crystal structure refinement has shown the zincophosphite with the composition +3NH(CH2)6+3NH[Zn(HPO3)2]2-, Mr=343.55. It crystallizes in monoclinic, space group C2/c (No. 15), a=2.2391 nm, b=0.8695 nm, c=0.7919 nm, =101.062(6), V=1.513 nm3, Dc=1.508 kg/m3, Z=4, F(000)=712, =1.849 mm-1, R1=0.0416, wR2=0.1023. This phase exhibits infinite inorganic chains of vertex-linked ZnO4 and HPO3. Via the electrostatic attraction, 1,6-hexamethylenediamine cations and inorganic chains construct a novel interesting two-dimensional inor-ganic-organic network.
A novel 1,6-hexamethylenediamine-zincophosphite has been synthesized hydrothermally. Its single-crystal structure refinement has shown the zincophosphite with the composition + 3NH (CH2) 6 + 3NH [Zn (HPO3) 2] 2-, Mr = 343.55. crystallizes in monoclinic space group C2 / c (No. 15), a = 2.2391 nm, b = 0.8695 nm, c = 0.7919 nm, = 101.062 6, V = 1.513 nm3, Dc = 1.508 kg / 4, F (000) = 712, = 1.849 mm-1, R1 = 0.0416, wR2 = 0.1023. This phase exhibits infinite inorganic chains of vertex-linked ZnO4 and HPO3. Via the electrostatic attraction, 1,6-hexamethylenediamine cations and inorganic chains construct a novel interesting two-dimensional inor-ganic-organic network.
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