Asymmetric bioreduction of substituted acenaphthenequinones using plant enzymatic systems:A novel st

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Regio-and enantioselective reduction of substituted acenaphthenequinones were conducted under mild reaction conditions using plant enzymatic systems.A screening of 15 plants allowed the selection of two suitable plants fulfilling enantiocomplementarity.The(+)-and(-)-mono hydroxyacenaphthenones were achieved with high conversion and good enantiomeric purity using peach(Prunus persica(L.)Batseh.,conversion 98%,71% ec)and carrot(Daucus carota L.,conversion 95%,81% ee),respectively.
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