Effects of Carrier on CuO/TiO_2 and CuO/Ti_(0.5)Zr_(0.5)O_2 Catalysts in the NO+CO Reaction

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:rwsonny
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Using TiO2 and Ti0.5Zr0.5O2 as carriers, the CuO/TiO2 and CuO/Ti0.5Zr0.5O2 catalystswere prepared by the impregnation method with Cu(NO3)2 as active component. The catalyticactivities in NO+CO reaction were investigated using a microreactor-GC system, and structure andreducibility of catalysts were characterized by means of physical adsorption, TPR, XRD, NO-TPDtechnologies. It was found that the activity of CuO/Ti0.5Zr0.5O2 catalyst was higher than that ofCuO/TiO2, probably due to the large specific surface area of Ti0.5Zr0.5O2 that played an importantrole in NO+CO reaction. The use of TiO2 and Ti0.5Zr0.5O2 as carriers, the CuO / TiO2 and CuO / Ti0.5Zr0.5O2 catalystswere prepared by the impregnation method with Cu (NO3) 2 as active component. The catalyticactivities in NO + CO reaction were investigated using a microreactor-GC system, and structure and predictability of the catalysts were characterized by means of physical adsorption, TPR, XRD, NO-TPD technologies. It was found that the activity of CuO / Ti0.5Zr0.5O2 catalyst was higher than that of CuO / TiO2, probably due to the large specific surface area of ​​Ti0.5Zr0.5O2 that played an importantrole in NO + CO reaction.
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