甲基丙烯酸丁酯和苯乙烯的原子转移自由基嵌段共聚

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活性聚合以其无链转移、无链终止和引发速度远大于增长速率的特点,应用于合成单分散聚合物、预定序列结构的嵌段共聚物等.常用的活性聚合方法如阴离子聚合、阳离子聚合及基团转移聚合对反应条件要求苛刻,不能用于丙烯酸酯类极性单体和苯乙烯类非极性单体的嵌段共聚.与... With its non-chain transfer chain, chainless termination and the trigger rate is much greater than the growth rate of the characteristics of the synthesis of monodisperse polymers, the sequence structure of the block copolymer. Commonly used living polymerization methods such as anionic polymerization, cationic polymerization and group transfer polymerization are demanding for reaction conditions and can not be used for the block copolymerization of acrylic polar monomers and styrenic non-polar monomers. versus...
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