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介绍了综合利用高Al低P含量的清平磷矿废料的一种简单可行的办法.在焙烧清平磷矿废料的硫酸浸取液中加入硫酸铵,在酸性条件下,在常压及5℃的低温下,使铝铵钒(NH4Al(SO4)2·12H2O)大量结晶,从而导致P和Al分离.到目前为止,Al2O3的总浸取率在80%以上,其回收率在90%以上.最后,从残余Fe3+、Al3+和部分SO2-4被除去的滤液中,通过石灰水分步中和、沉淀,能得到合格的饲料磷酸氢钙和磷肥.
A simple and feasible method to comprehensively utilize Qingping phosphorite waste with high Al and low P content is introduced. Ammonium sulfate is added to the sulfuric acid leaching solution for burning Qingping phosphate ore waste to crystallize a large amount of ammonium aluminum vanadium (NH4Al (SO4) 2 · 12H2O) under the condition of normal pressure and low temperature of 5 ° C under acidic conditions, resulting in P Separated from Al. So far, the total leaching rate of Al2O3 is above 80%, and the recovery rate is more than 90%. Finally, the filtrate from the residual Fe3 +, Al3 + and some SO2-4 is removed by stepwise neutralization and precipitation by lime water to obtain qualified feed DCP and phosphate fertilizer.