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以歧化松香胺席夫碱铜催化剂,H2O2(30%)氧化聚松香丙烯醇酯(PRAAE),得到聚松香丙烯醇酯氧化物。对聚合物进行了红外、紫外、软化点和热失重分析,BET法测定聚松香丙烯醇酯氧化物的微孔大部分分布在5nm以上;对聚松香丙烯醇酯氧化物相对分子质量进行了分析,其量在25266以上。结果表明所合成的聚松香丙烯醇酯氧化物为大孔聚合物。
The disproportionated rosin amine Schiff base copper catalyst, H2O2 (30%) oxidized rosin allyl ester (PRAAE), get rosin allyl alcohol ester oxide. The infrared, ultraviolet, softening point and thermogravimetric analysis of the polymers were carried out. The BET method was used to determine the micropores of the poly (rosin-co-propanol) oxide mostly distributed above 5nm. The relative molecular mass of the poly (rosin-co- , The amount of 25266 or more. The results show that the synthesized rosin allyl alcohol ester oxide is a macroporous polymer.