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以氯化锌和邻二氮菲为原料,在微波辅助作用下固相合成了二氯·邻二氮菲合锌(Ⅱ)配合物,利用红外光谱及单晶X射线法对目标化合物进行了表征,该配合物为单斜晶系,空间群为P21/n,晶体学参数:a=0.799 94(3)nm,b=1.570 14(5)nm,c=0.975 23(4)nm,β=101.353(2)°,F(000)=632,Z=4,V=1.200 94(8)nm3,Dc=1.750g·cm-3,Mr=316.47,最终结构偏离因子R=0.024 8,Rw=0.067 1,S=1.039,最终差值电子密度的最大值和最小值分别为274nm-3和-537nm-3.
Zinc (Ⅱ) dichloride and phenanthroline (Ⅱ) complexes were synthesized by solid state reaction using zinc chloride and phenanthroline as starting materials. The target compounds were characterized by IR and single crystal X-ray diffraction The complex is monoclinic with a space group of P21 / n. The crystallographic parameters are as follows: a = 0.799 94 (3) nm, b = 1.570 14 = 101.353 (2) °, F (000) = 632, Z = 4, V = 1.200 94 (8) nm3, Dc = 1.750 g · cm -3, Mr = 316.47, final structure departure factor R = 0.024 8, Rw = 0.067 1, S = 1.039. The maximum and minimum final electron density values were 274 nm-3 and -537 nm-3, respectively.