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The title compound C38H72N2PtS10(Mr=1072.74)crystallizes in triclinic system,space group P1 with cell constants a=11.994(4),b=18.117(7),c=11.855(6)A,α=95.55(4),β=99.14(3),γ=75.71(3)°,V=2460.0A3,Z=2 and Dc=1.45 gcm-3.The structure is solved by direct methods and refined by full-matrix least-squares technique to final R=0.046 and Rw=0.045 based on 5919 independent reflections with I≥3.0(I).The anion [Pt(C3S5)2]2-is approximately planar,of which the platinum-sulfur coordination polyhedron takes a square form with mean Pt-S bond length of 2.310(4)A.
The title compound C38H72N2PtS10 (Mr = 1072.74) crystallizes in the triclinic system space group P1 with cell constants a = 11.994 (4), b = 18.117 (7), c = 11.855 (6) A, = 99.14 (3), γ = 75.71 (3) °, V = 2460.0A3, Z = 2 and Dc = 1.45 gcm-3. The structure is solved by direct methods and refined by full-matrix least-squares technique to final R = 0.046 and Rw = 0.045 based on 5919 independent reflections with I ≥ 3.0 (I) .The anion [Pt (C3S5) 2] 2-is approximately planar, of which the platinum-sulfur coordination polyhedron takes a square form with mean Pt- S bond length of 2.310 (4) A.