STUDY ON 1,2,3-DIAZAPHOSFHOLE V THE REACTION OF 1,2,3-DIAZAPHOSPHOLE WITH 2-BUTYNE-1,4-DIOL

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:susanna2005
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2-Acetyl-5-methyl-2H-1,2,3—diaraphosphole 1 reacted with 2—butyne—1, 4—diol to form a tricoordinated phosphorus compound 7, which then rearranged to a novel 2, 3-disubstituted-1, 3-diene.Similar rearrangement has been observed when diphenylchloropbosphine
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