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A novel pyridine derivate,9-hexyl-3-((pyridin-4-yl)vinyl)-9H-carbazole,was synthesized and characterized by 1H NMR spectra and X-ray diffraction analysis.The complex crystallizes in monoclinic,space group P21/n with a=9.111(5),b=8.239(5),c=26.835(5) ,β=95.340(5)°,Mr=354.48,V=2005.6(17) 3,Z=4,Dc=1.174 g/cm3,μ=0.068 mm-1,F(000)=760,R=0.0565 and wR=0.1550 for 12635 observed reflections(Ⅰ>2σ(Ⅰ)).Density functional theory(DFT) calculations were carried out to interpret its UV-Vis spectra,and the results are in agreement with the available experiments.
A novel pyridine derivate, 9-hexyl-3- (pyridin-4-yl) vinyl) -9H-carbazole, was synthesized and characterized by 1H NMR spectra and X-ray diffraction analysis. The complex crystallizes in monoclinic, space group P21 / n with a = 9.111 (5), b = 8.239 (5), c = 26.835 (5) and β = 95.340 (5) °, Mr = 354.48 and V = 2005.6 (17) Density functional theory (DFT) calculations were carried out with Dc = 1.174 g / cm3, μ = 0.068 mm-1, F (000) = 760, R = 0.0565 and wR = 0.1550 for 12635 observed reflections out to interpret its UV-Vis spectra, and the results are in agreement with the available experiments.