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卤代芳烃用ＣＯ／ＨＣＯＯＮａ在饱催化下甲酰化ＯｋａｎｏＴ等［ＢｕｌｌＣｈｅｍＳｏｃＪｐｎ，１９９４；６７：２３２９］溴代及碘代芳烃用常压ＣＯ和ＨＣＯＯＮａ在ＤＭＦ中，经ＰｄＣｌ２（ＰＰｈ３）２催化，于１００～１１０℃脱卤生成相应的芳醛。芳环的邻位取代...
Carboxylation of haloaromatic hydrocarbons with CO / HCOONa under full catalysis OkanoT et al [BullChem Soc Jpn, 1994; 67: 2329] Bromo and iodoaromatic hydrocarbons are catalyzed by PdCl 2 (PPh 3) 2 at atmospheric pressure with CO and HCOONa in DMF Dehalogenation at 100-110 ° C produces the corresponding aromatic aldehyde. Adjacent aromatic ring replaced ...