超细粉体二硫纶 硝基菲咯啉铜(Ⅱ)配合物的光敏性研究

来源 :化学研究与应用 | 被引量 : 0次 | 上传用户:liping668
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
The microcrystalline structure of complex CuLL′(L=mnt2-,1,2-dicyano-1,2-ethylenedithiolate or maleonitriledithiolate.L′=5-NO2-phen,5-nitri-1,10-phenanthro line) was characterized by TEM and EDP.The title complex was microcrystalline particle approximate oval sphere about 30nm.The electronic absorption spectra and emission spectra of complex CuLL′in DMSO,DMF and CH3COCH3 were determined.The complex CuLL′exhibit strong absorption spectra bands and emission spectra bands at 260~530nm in solution.The dark conductivity and photoconductivity of CdS doped with CuLL′ were studied.The correlation between photosensitization of complex CuLL′to CdS and its electronic spectra was ascertained.The obvious matched properties was found to exist between the interligand charge transfer energy of complex CuLL′and forbidden band width(or photoconductive red limit) of CdS. The microcrystalline structure of complex CuLL ’(L = mnt2-, 1,2-dicyano-1,2-ethylenedithiolate or maleonitrilledithiolate. L’ = 5-NO2-phen, 5-nitri- 1,10-phenanthro line) was characterized by TEM and EDP.The title complex was microcrystalline particle approximate oval sphere about 30nm. The electronic absorption spectra and emission spectra of complex CuLL’in DMSO, DMF and CH3COCH3 were determined. The complex CuLL’hibhibit strong absorption spectra bands and emission spectra bands at 260 ~ 530nm in solution. The dark conductivity and photoconductivity of CdS doped with CuLL ’were studied. The correlation between photosensitization of complex CuLL’to CdS and its electronic spectra was ascertained. The obvious matched properties was found to exist between the interligand charge transfer energy of complex CuLL’and forbidden band width (or photoconductive red limit) of CdS.
其他文献
基于midplane网格类型,比较Hypermesh与Moldflow的网格前处理功能,从而说明使用Hypermesh作Moldflow的midplane网梏的前处理,可大大提高网格划分速度和网格质量,为Moldflow的
本文以1999年至2003年5年间日语能力测试1级试题中"阅读理解·语法"中的语法部分为考查对象,详细地考查、分析每年出现的语法项目的情况,发现其大致的命题走向,提出相应的对
本文提出语义创新可以作为衡量亲缘关系(genetic relationship)的特征。根据基本词的语义创新, 我们尝试以汉语方言为例探讨语言的亲缘关系,运用一个俭省(parsimonious)程序-
2005年5月到2006年4月逐月采样,运用一步法RT-PCR检测Citrus psorosis virus(CPV)在Dweet橘橙苗木叶片和枝皮中的分布.保存在控温温室中的Dweet橘橙病株中老叶、老皮、嫩叶和
现大量的力学教材仍在引用旧的GB228—1976,说明编辑与作者更应在GB内容上进行深入细致的沟通。读者需要新的GB228—1987中的技能知识。 Now a large number of mechanical
President Roosevelt ranked as one of American greatest presidents due to his New Deal in the Great Depression. Actually, his New Deal did not cure the nation' s
飘窗是如今很多房型中必备的设计。所谓飘窗,一般是指房间中向外的凸出部分,大都呈矩形或梯形,与传统的窗户不同,这里三面都装有玻璃,视野更加开阔,灵活性也便多了许多。虽然
近年来,全省组织系统以贯彻党的十七大和十七届四中全会精神为主线,围绕中心、服务大局,注重改革创新、注重为民服务、注重工作落实,各项工作都取得显著成效。学习实践科学发展观
为了使单色仪在极紫外-软X射线波段准确地进行波长扫描,需要对单色仪进行波长标定。单色仪的所有组件都放置在罗兰圆的圆周上,改变出射狭缝在罗兰圆上的位置,在单色仪的出射
Q:我的超低音音箱是无源的,而低音单元的口径比较大,朋友推荐我使用一台专业功放来驱动(例如Crown、AB、LAB.GRUPPEN等),请问使用这些功放是否可行?据闻超低音音箱对放大器的输出功率